What does the Windows Disk Management program (enter diskmgmt.msc at a command prompt) show for this drive? The 200 MiB size sounds to me as though you may have formatted your USB drive with partitioning instead of. In that case OS X may have slipped a 200 MB 'EFI partition' ahead of your FAT partition. If Disk Management shows you that the USB drive uses GPT partitioning and there are two partitions, a 200 MiB partition followed by a 3,614 MiB (3.53 GiB) FAT partition, then that is what happened.
NTFS: The NT File System (NTFS) is the file system that modern Windows versions use by default. HFS+: The Hierarchical File System (HFS+) is the file system modern macOS versions use by default. APFS: The proprietary Apple file system developed as a replacement for HFS+, with a focus on flash drives, SSDs, and encryption. APFS was released with iOS 10.3 and macOS 10.13, and will become the mandatory file system for those operating systems. To create bootable USB drive for windows, make sure that your USB/DVD is at least 8GB or larger and working fine. You can also do it from our previous article based on How to Create After restarting your USB flash drive will be bootable successfully and you can use it to install Mac on any PC.
If that is the problem then I suggest you use MBR partitioning when you format on a Mac. Using Disk Utility before you apply the partitioning you would click on the 'Options' button (underneath the 'Volume Scheme' graphic to the right of the '+' & '-' buttons) and select 'Master Boot Record'.
What Is ExFAT? Microsoft's exFAT is a file system designed for cross-platform mobile personal storage.
The exFAT format is designed for high-capacity flash drives, memory cards, and external hard drives. The format is designed to require minimal adjustments to add support from Microsoft's widely used FAT32 format on the developer and manufacturer side. ExFAT improves on many of the FAT32 format's limitations, including increasing the maximum storage capacity per partition or reserved section from 32 gigabytes to 256 terabytes. External hard drives benefit from exFAT because you can set them up with large partitions that can contain the entire device - instead of in 32GB sections in FAT32 - and maintain compatibility between Macs and PCs. Format to ExFAT on Windows 8 Windows 8's included Disk Management tool can format devices to exFAT. To format an external hard drive to exFAT with the tool, connect the hard drive to the computer, press 'Windows-R,' then type 'diskmgmet.msc' and select 'OK.' After the Disk Management program has launched, right-click on the external hard drive's partition graphic box.
The hard drive partitions are listed on the lower section of the Window. Recently attached devices will appear at the bottom of the list and the partition will be marked with the dark blue color bar on the top of the box. Select the 'Format.' Option from the menu. Change the 'File System' drop menu to 'ExFAT' and press 'OK' to format the drive.
Warnings and Tips Backup any data on the external hard drive you want to keep on another device before formatting. Formatting a hard drive will erase all data that's stored on it. Both Windows 8 and Mac OS X allow you to adjust the size of the format partitions on external hard drives.
Set the number to the maximum to use the entire drive in a single partition. FAT32-formatted drives also work for PC-and-Mac sharing, in particular with older versions of both operating systems. However, Microsoft recommends against using FAT32 whenever possible in favor of exFAT.